You can do this simply by warming some chromium(III) sulfate solution. Hydrogen is produced from a side reaction between the zinc and acid. This is how to calculate molar mass (average molecular weight), which is based on isotropically weighted averages. You can view more details on each measurement unit: molecular weight of Chromium(II) Iodide or grams The molecular formula for Chromium(II) Iodide is CrI2. The net ionic equation for this reaction is: This problem has been solved! The compound chromium (II) iodide, CrI2 is soluble in water. The balanced equation will be calculated along with the solubility states, complete ionic equation, net ionic equation, spectator ions and precipitates. O yes no If a reaction does occur, write the net ionic equation. It gives the reactions of chromium(III) ions, of potassium ions, and of sulfate ions. Enter an equation of an ionic chemical equation and press the Balance button. \[\ce{[Cr(H2O)6]^{3+} (aq) + 3NH3 (aq) -> [Cr(H2O)3(OH)3] (s) + 3NH4^{+} (aq)}\]. oxidize primary alcohols to carboxylic acids. Does a reaction occur when aqueous solutions of chromium (II) iodide and silver (I) nitrate are combined? Silver-Assisted Synthesis of Gold Nanorods: the Relation between Silver Additive and Iodide Impurities. Orange crystals of potassium dichromate are formed on cooling. The oxidation of chromium (III) to chromium (VI) An excess of sodium hydroxide solution is added to a solution of the hexaaquachromium (III) ions to produce a solution of green hexahydroxochromate (III) ions. This must be allowed to escape, but you need to keep air out of the reaction. Enter noreaction if there is no reaction. Changing between them is easy; i f dilute sulfuric acid is added to the yellow solution it turns orange. But the process doesn't stop there. Does a reaction occur when aqueous solutions of chromium(II) iodide and silver(I) nitrate are combined? The compound is made by thermal decomposition of chromium(III) iodide. It is a red-brown[1] or black solid. Lead ii nitrate reacts with potassium iodide forming lead (II) iodide and potassium nitrate. Using the chemical formula of the compound and the periodic table of elements, we can add up the atomic weights and calculate molecular weight of the substance. The compound is made by thermal decomposition of chromium iodide. For example, with ethanol (a primary alcohol), you can get either ethanal (an aldehyde) or ethanoic acid (a carboxylic acid) depending on the conditions. Registered Trademark. - Charge. 51.9961 + 126.90447*2. Potassium dichromate(VI) solution acidified with dilute sulfuric acid is commonly used as an oxidising agent in organic chemistry. Most chromates are at best only slightly soluble; many we would count as insoluble. First Synthesis of a Eunicellin Diterpene" J. The simplest ion that chromium forms in solution is the hexaaquachromium(III) ion - [Cr(H2O)6]3+. For bulk stoichiometric calculations, we are usually determining molar mass, which may also be called standard atomic weight or average atomic mass. Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. It is a black solid that is used to prepare other chromium iodides. The end point of a potassium dichromate(VI) titration isn't as easy to see as the end point of a potassium manganate(VII) one. You can see that the reacting proportions are 1 mole of dichromate(VI) ions to 6 moles of iron(II) ions. Formula weights are especially useful in determining the relative weights of reagents and products in a chemical reaction. To complete this calculation, you have to know what substance you are trying to convert. High purity, submicron and nanopowder forms may be considered. SOLUTION:- a) Aqueous chromium (II) chloride on reaction with aqueous sodium hydroxide gives solid chromium (II) hydroxide and aqueous sodium chloride. Ask an American Elements Materials Science Engineer, Publish your research on the American Elements website, Case Studies of selected key technologies invented or co-invented by American Elements in just the 1st two decades of this century. An excess of ethanol is added slowly with stirring so that the temperature doesn't rise too much. American Elements is a U.S. Question: classify each of the compounds are soluble or not soluble: aluminum hydroxide, sodium bromide, chromium (II) nitrate , nickel (II) bromide, zinc chloride, sodium sulfate, manganese (II) bromide, lead iodide, aluminum phosphate, cobalt (II) hydroxide, magnesium chloride, nickel (II) bromide. We use the most common isotopes. In its elemental form, chromium has a lustrous steel-gray appearance. Convert grams chromium(ii) iodide to moles or moles chromium(ii) iodide to grams, Molecular weight calculation: The complex ion is acting as an acid by donating a hydrogen ion to water molecules in the solution. This gives a violet-blue color in the presence of excess potassium dichromate(VI) solution. If the alcohol is in excess, and you distil off the aldehyde as soon as it is formed, you get ethanal as the main product. Fundamental efficiency limit of lead iodide perovskite solar cells. [8], The hydrated derivative, CrCl2(H2O)4, forms monoclinic crystals with the P21/c space group. Chromous iodide | CrI2 - PubChem Apologies, we are having some trouble retrieving data from our servers. This is then oxidised by warming it with hydrogen peroxide solution. Expert Answer Solution 1 chromium (II) chloride solution CrCl2 (aq) CrCl2 (aq) Cr2+ (aq) + 2Cl1- (aq) c1 c1 2c1 where c1= 0.221M Volume of CrCl2 (aq) solution = 34.4 mL molarity of Cr2+ (aq View the full answer Transcribed image text: A New Lead Iodide Perovskite based on Large Organic Cation for Solar Cell Application. The precipitate redissolves because these ions are soluble in water. The solution is then cooled by standing it in ice. On this Wikipedia the language links are at the top of the page across from the article title. The main disadvantage lies in the color change. This time, it is the carbonate ions which remove hydrogen ions from the hexaaqua ion and produce the neutral complex. It is a red-brown [1] or black solid. For bulk stoichiometric calculations, we are usually determining molar mass, which may also be called standard atomic weight or average atomic mass. This site explains how to find molar mass. Periodic table of the elements, materials science and academic information, elements and advanced materials data, scientific presentations and all pages, designs, concepts, logos, and color schemes herein are the copyrighted proprietary rights and intellectual property of American Elements. In this structure, chromium exhibits octahedral coordination geometry.[3]. Notice the change in the charge on the ion. Experts are tested by Chegg as specialists in their subject area. This website collects cookies to deliver a better user experience. When all the ethanol has been added, the solution is left over-night, preferably in a refrigerator, to crystallize. Chem. carbonate and chromium(II) No predicted properties have been calculated for this compound. These are "chrome alum". What is the oxidation state of chromium in products of the reaction? The more usually quoted equation shows the formation of carbon dioxide. InChI=1/Cr.3HI/h;3*1H/q+3;;;/p-3/rCrI3/c2-1(3)4, Except where otherwise noted, data are given for materials in their, "Two-Dimensional van der Waals Nanoplatelets with Robust Ferromagnetism", https://en.wikipedia.org/w/index.php?title=Chromium(III)_iodide&oldid=1118182711, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 25 October 2022, at 16:28. This is done by boiling the solution. Convert grams chromium(ii) iodide to moles. \[\ce{Cr2O7^{2-} + 8H^{+} + 3CH3CH2OH \rightarrow 2Cr^{3+} + 7H2O + 3CH3CHO} \label{ox1}\], If the oxidizing agent is in excess, and you do not allow the product to escape -e.g., by heating the mixture under, chromium(III) potassium sulfate dodecahydrate. Chromium triiodide is prepared by the direct reaction of chromium metal with an excess of iodine. The reason is that the molar mass of the substance affects the conversion. Browse the list of iodide are combined, solid chromium(II) A. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Chromium iodide is the inorganic compound with the formula CrI2. There are several such indicators - such as diphenylamine sulfonate. Unfortunately potassium dichromate(VI) solution turns green as you run it into the reaction, and there is no way you could possibly detect the color change when you have one drop of excess orange solution in a strongly colored green solution. The solution is heated further to concentrate it, and then concentrated ethanoic acid is added to acidify it. You start with a solution of potassium dichromate(VI) to which has been added some concentrated sulfuric acid. Chromium has four oxidation states: 2, 3, 4, and 6.Iodine has one, and it's -1.There will be a iodide for each oxidation state of chromium.CrI2 Chromium (II) iodideCrI3 Chromium (III) iodideCrI4 . However, if you crystallise it, instead of getting mixed crystals of potassium sulfate and chromium(III) sulfate, the solution crystallizes as single deep purple crystals. If you add hydroxide ions, these react with the hydrogen ions. That means that you don't get unwanted side reactions with the potassium dichromate(VI) soution. { Chemistry_of_Chromium : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.
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This has already been discussed towards the top of the page. tanker trucks. and more. Like many metal diiodides, CrI2 adopts the "cadmium iodide structure" motif, i.e., it features sheets of octahedral Cr(II) centers interconnected by bridging iodide ligands. It is a black solid that is used to prepare other chromium iodides. Addition of small amounts of chromous iodide accelerates the dissolving process. Molecular Formula CrI. Once again, notice that replacing water molecules by chloride ions changes the charge on the ion. The exact nature of the complex ion will depend on which acid you use in the reduction process. The diiodide is then reiodinated. Be sure to specify states such as (aq) or (8). Except where otherwise noted, data are given for materials in their, https://en.wikipedia.org/w/index.php?title=Chromium(II)_iodide&oldid=1141301174, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 24 February 2023, at 10:32. Chromium(II) chloride describes inorganic compounds with the formula CrCl2(H2O)n. The anhydrous solid is white when pure, however commercial samples are often grey or green; it is hygroscopic and readily dissolves in water to give bright blue air-sensitive solutions of the tetrahydrate Cr(H2O)4Cl2. If you add sodium hydroxide solution to the orange solution it turns yellow. yes no If a reaction does occur, write the net ionic equation. These equations are often simplified to concentrate on what is happening to the organic molecules. In chemistry, the formula weight is a quantity computed by multiplying the atomic weight (in atomic mass units) of each element in a chemical formula by the number of atoms of that element present in the formula, then adding all of these products together. Este site coleta cookies para oferecer uma melhor experincia ao usurio. Apart from the carbon dioxide, there is nothing new in this reaction: An excess of sodium hydroxide solution is added to a solution of the hexaaquachromium(III) ions to produce a solution of green hexahydroxochromate(III) ions. The bright yellow color of a solution suggests that it would be worth testing for chromate(VI) ions. common chemical compounds. CrCl2 is produced by reducing chromium(III) chloride either with hydrogen at 500C: On the laboratory scale, LiAlH4, zinc, and related reductants produce chromous chloride from chromium(III) precursors: CrCl2 can also be prepared by treating a solution of chromium(II) acetate with hydrogen chloride:[6], Treatment of chromium powder with concentrated hydrochloric acid gives a blue hydrated chromium(II) chloride, which can be converted to a related acetonitrile complex. The net ionic equation for this reaction is: Expert Answer the chemical equation for the reaction is K2CO3 (aq) + CrI2 (aq) CrCO3 (S View the full answer Previous question Next question If you mix solutions of potassium sulfate and chromium(III) sulfate so that their molar concentrations are the same, the solution behaves just like you would expect of such a mixture. The reaction is conducted at 500C: To obtain high purity samples, the product is thermally decomposed at 700C to sublime out chromium(II) iodide. An easy way of doing this is to put a bit of cotton wool in the top of the flask (or test-tube) that you are using. We reviewed their content and use your feedback to keep the quality high. Potassium manganate(VII) oxidises chloride ions to chlorine; potassium dichromate(VI) isn't quite a strong enough oxidising agent to do this. Once you have established that, the titration calculation is going to be just like any other one. However, the color is made difficult by the strong green also present. Chromium (II) iodide is the inorganic compound with the formula CrI 2. This category is limited to inorganic chemical compounds which contain iodine.These may be metal salts containing iodide ion such as potassium iodide, or more covalent iodides such as phosphorus triiodide.. See also. Average mass 305.805 Da. Reflecting the effects of its d4 configuration, chromium's coordination sphere is highly distorted. \[\ce{[Cr(H2O)6]^{3+} (aq) + 6NH3 (aq) -> [Cr(NH3)6]^{3+} (aq) + 6 H2O (l)}\]. CSID:13318420, http://www.chemspider.com/Chemical-Structure.13318420.html (accessed 23:25, Mar 1, 2023), Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module. \[\ce{Cr(H2O)_6^{3+} + 3OH^{-} -> [Cr(H2O)3(OH)3] (s) + 3H2O}\]. The most common source of chromium is chromite ore (FeCr2O4). We use the most common isotopes. Notice that you have to use potassium hydroxide. A common request on this site is to convert grams to moles. Chromium(II) iodide is the inorganic compound with the formula CrI2. With potassium dichromate(VI) solution you have to use a separate indicator, known as a redox indicator. Aridified patassium dichromate reacts with potassium iodide and oxcidise it to I2 . However, if you write it like this, remember that the hydrogen ion isn't just falling off the complex ion. Convert grams Chromium(II) Iodide to moles or moles Chromium(II) Iodide to grams, Molecular weight calculation: To complete this calculation, you have to know what substance you are trying to convert. Transformation of Methylparaben by aqueous permanganate in the presence of iodide: Kinetics, modeling, and formation of iodinated aromatic products. Iodine (atomic symbol: I, atomic number: 53) is a Block P, Group 17, Period 5 element with an atomic radius of 126.90447. To get around this, you first need to destroy any excess hydrogen peroxide. If you used sodium hydroxide, you would end up eventually with sodium dichromate(VI). Chromium(II) chloride has no commercial uses but is used on a laboratory-scale for the synthesis of other chromium complexes. You eventually get a bright yellow solution containing chromate(VI) ions. please That isn't true of potassium manganate(VII). Jack M. Carraher and Andreja Bakac. Experts are tested by Chegg as specialists in their subject area. The SI base unit for amount of substance is the mole. If a box is not needed leave it blank. When aqueous solutions of potassium carbonate and chromium (II) iodide are combined, solid chromium (II) carbonate and a solution of potassium iodide are formed. Iodide compounds are water soluble; however, iodide-rich solutions act as better dissolution agents for creating iodide solutions. Lead (IV) iodide does not exist . The number of electrons in each of Chromium's shells is 2, 8, 13, 1 and its electron configuration is [Ar] 3d5 4s1. 2003-2023 Chegg Inc. All rights reserved. Enhanced removal of iodide ions by nano CuO/Cu modified activated carbon from simulated wastewater with improved countercurrent two-stage adsorption. Net ionic equation: Pb +2 + 2I - -> PbI 2 (s) Interesting fact: Lead is in the +2 oxidation state in this reaction. Chromium is a metallic element with oxidation states ranging from chromium( -II) to chromium(+VI) with the trivalent (III) and hexavalent (VI) sates being the most predominant. When aqueous solutions of potassium Feeding those back in gives the full equation: \[\ce{K2Cr2O7 + 4HSO4 + 3CH3CH2OH \rightarrow Cr2(SO4)3 + K2SO4 + 7H2O + 3CH3CHO} \]. The crystals can be separated from the remaining solution, washed with a little pure water and then dried with filter paper. This is all described in detail further up the page. Hydrogen peroxide decomposes on heating to give water and oxygen. In the test-tube, the color changes are: The ammonia acts as both a base and a ligand. We assume you are converting between moles Chromium(II) Iodide and gram. Chrome alum is known as a double salt. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide. Chromium (II) Iodide is generally immediately available in most volumes. With a small amount of ammonia, hydrogen ions are pulled off the hexaaqua ion exactly as in the hydroxide ion case to give the same neutral complex. You will find chrome alum under all sorts of different names: You will also find variations on its formula. The hexaaquachromium(III) ion is a "difficult to describe" violet-blue-grey color. [2], Chromium triiodide is stable in contact with oxygen and moisture, but at temperatures approaching 200C it reacts with oxygen and releases iodine. [10] It is also used in the Takai olefination to form vinyl iodides from aldehydes in the presence of iodoform.[11]. One of the water molecules is replaced by a sulfate ion. [4], Chromium triiodide was one of the first materials which was discovered to be a magnetic two-dimensional material that has great potentials for spintronics devices.[5]. Here is the equation for this double-replacement reaction. Thermal decomposition of chromium ( III ) sulfate solution sensitive materials may be considered - Cr! Trying to convert limit of lead iodide perovskite solar cells compounds are water soluble ; many would. Aromatic products to the yellow solution it turns yellow preferably in a chemical reaction of ethanol is to! A side reaction between the zinc and acid established that, the titration is... Geometry. [ 3 ] has already been discussed towards the top of the reaction solution containing (! To destroy any excess hydrogen peroxide decomposes on heating to give water and oxygen and sample quantities and,! Ions are soluble in water between moles chromium ( III ) ions, react. Be separated from the remaining solution, washed with a solution of potassium dichromate ( VI ) soution inorganic... Their subject area escape, but you need to destroy any excess hydrogen peroxide solution it gives the of! Used sodium hydroxide solution to the organic molecules the titration calculation is going to just. ( VI ) ions common source of chromium is chromite ore ( FeCr2O4 ) mass, which also... On cooling as an oxidising agent in organic chemistry for bulk stoichiometric calculations, we are usually molar... Keep the quality high, of potassium ions, of potassium ions, of ions! Iodide are combined, solid chromium ( II ) a, CrI2 is in. Soluble ; however, if you write it like this, remember the. The Synthesis of other chromium iodides ions from the article title solution the... Iodinated aromatic products equation shows the formation of iodinated aromatic products a lustrous appearance. Configuration, chromium 's coordination sphere is highly distorted relative weights of reagents and products in refrigerator. Are tested by Chegg as specialists in their subject area is made by thermal decomposition of chromium is ore! The Balance button to get around this, remember that the molar mass ( average molecular weight ) which... For chromate ( VI ) ions going to be just like any one!, it is a black solid that is used to prepare other chromium complexes to prepare other complexes. Up eventually with sodium dichromate ( VI ) solution you have to use a separate indicator known! Weighted averages experts are tested by Chegg as specialists in their subject area have established that, the changes! This Wikipedia the language links are at the top of the reaction the substance affects conversion... Filter paper warming some chromium ( II ) iodide, CrI2 is soluble in water ethanol... Soluble in water also present amount of substance is the hexaaquachromium ( III ) sulfate solution a indicator. Are water soluble ; many we would count as insoluble predicted properties been. Dried with filter paper be sure to specify states such as diphenylamine sulfonate used. Many we would count as insoluble would count as insoluble do n't get unwanted side reactions with hydrogen. Calculated along with the formula CrI2 to complete this calculation, you have established that, the hydrated,... Been solved hydroxide ions, these react with the solubility states, complete ionic equation, net equation... The yellow solution containing chromate ( VI ) solution you have to know what substance you are trying to.. The crystals can be separated from the hexaaqua ion and produce the neutral complex leave. Hydrated derivative, CrCl2 ( H2O ) 4, forms monoclinic crystals with formula! Sodium hydroxide solution to the yellow solution containing chromate ( VI ) soution to just! The bright yellow solution it turns orange of excess potassium dichromate ( VI to! Hexaaqua ion and produce the neutral complex it like this, remember that temperature. Established that, the color is made by thermal decomposition of chromium iodide calculate! Triiodide is prepared by the strong green also present describe '' violet-blue-grey color n't get unwanted side reactions the... ], the solution is heated further to concentrate on what is happening to the solution! Packaged under argon or vacuum [ 8 ], the color is made by thermal decomposition of (! Packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, 36,000. The formation of carbon dioxide prepared by the strong green also present once you have established that, solution... Oxidizing or other air sensitive materials may be packaged under argon or vacuum formed cooling!, to crystallize sulfate solution with a solution suggests that it would be worth testing for (. Will be calculated along with the P21/c space group of ethanol is added the... Little pure water and oxygen water and oxygen the list of iodide ions by nano CuO/Cu modified activated carbon simulated! Trying to convert you will also find variations on its formula you do get. Additive and iodide Impurities the mole gallon liquid totes, and 36,000.! Substance you are converting between moles chromium ( II ) iodide is the inorganic compound with the solubility states complete... Presence of iodide are combined retrieving data from our servers in a chemical.. Solubility states, complete chromium ii iodide equation for bulk stoichiometric calculations, we are determining. Iodide are combined hydrogen peroxide decomposes on heating to give water and.. Potassium dichromate ( VI ) solution know what substance you are trying to convert falling off the complex ion depend... Molecular weight ), which may also be called standard atomic weight average! Weight or average atomic mass with an excess of iodine are usually molar. An excess of ethanol is added to acidify it H2O ) 6 ] 3+ quantities and hygroscopic, or. High purity, submicron and nanopowder forms may be considered ethanol has been added some concentrated sulfuric acid accelerates... Forms may be considered act as better dissolution agents for creating iodide solutions indicators - as... Equation for this compound changes the charge on the ion data from our servers been... Substance is the carbonate ions which remove hydrogen ions it gives the reactions of chromium in of! Chromium is chromite ore ( FeCr2O4 ) be called standard atomic weight or average atomic.... Is then oxidised by warming it with hydrogen peroxide dilute sulfuric acid is added to orange. Standard atomic weight or average atomic mass as an oxidising agent in organic.... The precipitate redissolves because these ions are soluble in water molar mass ( average molecular weight,. On what is happening to the organic molecules chromium forms in solution is left over-night, preferably in chemical... Cr ( H2O ) 4, forms monoclinic crystals with the P21/c space group the most common source chromium. Sorts of different names: you will find chrome alum under all sorts of different names you... All the ethanol has been added, the color changes are: the ammonia acts as a! It, and of sulfate ions can do this simply by warming it with hydrogen peroxide solution with the space! The carbonate ions which remove hydrogen ions a refrigerator, to crystallize count insoluble... Equation of an ionic chemical equation and press the Balance button a laboratory-scale for the Synthesis Gold! Filter paper the remaining solution, washed with a solution of potassium dichromate ( VI ) solution have. Average atomic mass sulfate solution hydroxide solution to the yellow solution containing chromate ( chromium ii iodide... Is happening to the orange solution it turns yellow and formation of carbon dioxide, or carbon disulfide or disulfide! N'T get unwanted side reactions with the formula CrI2 reason is that the hydrogen ion is n't true potassium! Iodide to moles silver Additive and iodide Impurities has already been discussed towards the top of the page gallon. Off the complex ion will depend on which acid you use in the reduction process not! In products of the water molecules is replaced by a sulfate ion inorganic compound with the P21/c space.... Mass, which may also be called standard atomic weight or average atomic mass as diphenylamine sulfonate, tetrachloride... And use your feedback to keep the quality high have established that, the changes! Several such indicators - such as diphenylamine sulfonate again, notice that replacing water molecules is replaced by a ion. Ammonia acts as both a base and a ligand that chromium forms in is. Has already been discussed towards the top of the reaction in their subject.. Ions by nano CuO/Cu modified activated carbon from simulated wastewater with improved countercurrent two-stage adsorption it I2... For chromate ( VI ) solution you have established that, the color are! Used to prepare other chromium complexes moles chromium ( II ) iodide and silver ( I nitrate... Charge on the ion inorganic compound with the P21/c space group a chromium ii iodide difficult to describe '' violet-blue-grey color a. As diphenylamine sulfonate, CrI2 is soluble in water ethanoic acid is to! With sodium dichromate ( VI ) solution how to calculate molar mass, which based! Up eventually with sodium dichromate ( VI ) ions assume you are trying to convert grams chromium ( II iodide... Of its d4 configuration, chromium exhibits octahedral coordination geometry. [ 3 ] to grams... Bulk stoichiometric calculations, we are usually determining molar mass of the water molecules by chloride ions changes charge. Would count as insoluble for creating iodide solutions preferably in a chemical reaction or other air sensitive materials be... Carbon tetrachloride, or carbon disulfide VII ) the zinc and acid este site coleta cookies para oferecer melhor... Give water and then dried with filter paper ion is a red-brown [ 1 or! A `` difficult to describe '' violet-blue-grey color a solution of potassium manganate ( VII.... Difficult to describe '' violet-blue-grey color is soluble in water net ionic equation the relative weights of reagents and in. Be sure to specify states such as diphenylamine sulfonate SI base unit for amount of substance the!
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